the settings are only part of the story. there are other factors which, presumably, would be detailed in the server's documentation. what you've tried so far seems to conform to the settings you show, so you'll have to read the rest of the documentation. when you use your smtp server from outside its network, success is not always based simply on login/password. it goes back many years to a time when, eg, i could use your smtp server to send spam. it was called relaying. in those days, you didn't even need a login/password. protections have since been put in place.
take gmail, for example: you have to have authorization from google to use gmail as an smtp server from an app. it doesn't matter that you have a login/password. your server may have a similar requirement. if i were an smtp server, i know i would.
some stmp servers require checking for mail (pop) before they allow outgoing mail (smtp). it's called pop over smtp. your server could have such a requirement.
if you don't want to check the documentation, you should ask the smtp administrator what you have to do to send email from an email client.